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Sorry webgirl - I'm using it quite successfully on LAMP - maybe a permissions issue with the target directory for the upload? I know there are plenty of WAMP users here though - so hopefully you'll hear from someone else as well!
Report your issues and feature requests; https://github.com/opencats/opencats/issues
Any updates on this. I am having the same issue but do not want to change permissions too much. I am going to try copying cmd.exe into the antiword directory change the permissions and see if that might help.